Sustainable ammonia can be produced today: doing so would use electrolyzers to make hydrogen to feed the traditional Haber-Bosch process. In a very few years, new technologies will skip this hydrogen production phase altogether and make ammonia directly from renewable power in an electrochemical cell. Further down the pipeline, next generation technologies will mimic nature, specifically the nitrogenase enzyme, which produces ammonia naturally.
One of these next generation technologies is currently producing impressive results at the US Department of Energy's (DOE) National Renewable Energy Laboratory (NREL).
New research coming out of Stanford University suggests a fascinating new direction for electrochemical ammonia synthesis technology development.
The US-Danish team of scientists at SUNCAT, tasked with finding new catalysts for electrochemical ammonia production, saw that 'selectivity' posed a tremendous challenge - in other words, most of the energy used by renewable ammonia production systems went into making hydrogen instead of making ammonia.
The new SUNCAT solution does not overcome this selectivity challenge. It doesn't even try. Instead, these researchers have avoided the problem completely.
A new collaboration was announced last week, between Dutch power company Nuon, European natural gas pipeline operator Gasunie, and Norwegian oil major Statoil. The joint venture will look at converting one of the Magnum power plant's three 440 MW gasifiers, with hopes to have it running on hydrogen fuel by 2023.
This is the continuation of the Power to Ammonia project and, although ammonia is not expected to be used in this particular stage of the project, converting Magnum to hydrogen fuel represents the "intermediate step" to demonstrate that "where hydrogen could be produced using natural gas by 2023, from the year 2030 it could be possible to produce it with sustainably produced ammonia ... Ammonia then effectively serves as a storage medium for hydrogen, making Magnum a super battery."
The American Chemical Society (ACS) has published the program for its 2017 National Meeting, which takes place next month in Washington DC and includes a session dedicated to the "Ammonia Economy."
The first day of the week-long meeting, Sunday August 20th, will feature a full morning of technical papers from the US, UK, and Japan, covering ammonia energy topics across three general areas: producing hydrogen from ammonia, developing new catalysts for ammonia synthesis and oxidation, and storing ammonia in solid chemical form.
The International Energy Agency (IEA) has just published Energy Technology Perspectives 2017, the latest in its long-running annual series, subtitled "Catalysing Energy Technology Transformations."
In this year's edition, for the first time, ammonia is featured in two major technology transformations. First, ammonia production is shown making a significant transition away from fossil fuel feedstocks and towards electrification, using hydrogen made with electrolyzers. And, following this assumption that sustainable ammonia will be widely available in the future, the IEA takes the next logical step and also classifies ammonia "as an energy carrier," in the category of future "electricity-based fuels (PtX synthetic fuels)."
The inclusion of this pair of technology transformations represents a major step towards broader acceptance of ammonia as an energy vector, from the perspectives of both technical feasibility and policy imperative.
The viability of producing ammonia using renewable energy was one of the recurring themes of the recent Power to Ammonia conference in Rotterdam. Specifically, what cost reductions or market mechanisms would be necessary so that renewable ammonia - produced using electrolytic hydrogen in a Haber-Bosch plant - would be competitive with normal, "brown" ammonia, made from fossil fuels.
A number of major industry participants addressed this theme at the conference, including Yara and OCI Nitrogen, but it was the closing speech, from the International Energy Agency (IEA), that provided the key data to demonstrate that, because costs have already come down so far, renewable ammonia is cost-competitive in certain regions today.
The maritime industry is beginning to show significant interest in using ammonia as a "bunker fuel," a sustainable alternative to the highly polluting heavy fuel oil (HFO) currently used in ships across the world.
In recent months, a firm of naval architects and a new maritime think tank have both been evaluating ammonia as a fuel. This includes a road map for future research, and collaborations for a demonstration project that will allow them to design and build a freight ship "Powered by NH3."
One of the many encouraging announcements at the recent Power-to-Ammonia conference in Rotterdam was the news that the Korea Institute of Energy Research (KIER) has extended funding for its electrochemical ammonia synthesis research program by another three years, pushing the project forward through 2019.
KIER's research target for 2019 is significant: to demonstrate an ammonia production rate of 1x10-7 mol/s·cm2.
If the KIER team can hit this target, not only would it be ten thousand times better than their 2012 results but, according to the numbers I'll provide below, it would be the closest an electrochemical ammonia synthesis technology has come to being commercially competitive.
The Institute for Sustainable Process Technology (ISPT) recently published a detailed analysis of three business cases for producing renewable ammonia from electricity: Power to Ammonia. The feasibility study concludes that, in the near term, ammonia production using clean electricity will likely rely on a combination of two old-established, proven technologies: electrolysis and Haber-Bosch (E-HB). To reach this conclusion, however, the study also assessed a range of alternative technologies, which I summarize in this article.