A recent Ammonia Energy post mentioned that in December 2017 “the Japanese government . . . approved an updated hydrogen strategy which appears to give ammonia the inside track in the race against liquid hydrogen (LH2) and liquid organic hydride (LOH) energy carrier systems.” While this news is positive, the hydrogen strategy remains the essential context for economic implementation of ammonia energy technologies in Japan; ammonia’s prospects are only as bright as those of hydrogen. This is why Ammonia Energy asks from time to time, how is hydrogen faring in Japan?
Proton Ventures and Delft University of Technology (TU Delft), both of the Netherlands, announced in early February the formation of a new company, Battolyser B.V. The company’s initial goal is to build and demonstrate a pilot version of the eponymous technology that stores electricity and produces hydrogen. Hans Vrijenhoef, who will direct the new company, indicated that a fully realized system would include an ammonia production train so that the hydrogen could be stored and transported at low cost. Vrijenhoef is already the Director of Proton Ventures B.V., a member of the NH3 Fuel Association’s Global Federation Advisory Board, and the originator of the NH3 Event power-to-ammonia conference.
This week, the government of South Australia announced a "globally-significant demonstrator project," to be built by the hydrogen infrastructure company Hydrogen Utility (H2U). The renewable hydrogen power plant will cost AUD$117.5 million ($95 million USD), and will be built by ThyssenKrupp Industrial Solutions with construction beginning in 2019.
The plant will comprise a 15 MW electrolyzer system, to produce the hydrogen, and two technologies for converting the hydrogen back into electricity: a 10MW gas turbine and 5MW fuel cell. The plant will also include a small but significant ammonia plant, making it "among the first ever commercial facilities to produce distributed ammonia from intermittent renewable resources."
During his presentation at the November 2017 NH3 Energy + Topical Conference, Shogo Onishi of IHI Corporation described the progress made by IHI and Tohoku University in limiting NOx emissions from ammonia-fired gas turbines (AGTs). Regular attendees of the annual NH3 Fuel Conference identify IHI with its work on AGTs since the company also addressed this topic at the 2016 and 2015 events. However, a scan of published materials shows that AGTs are just one aspect of IHI’s activity in the ammonia energy arena. In fact, IHI is also looking at the near-term commercialization of technologies in ammonia-coal co-firing in steam boilers and direct ammonia fuel cells. This level and breadth of commitment to ammonia energy is unique among global capital goods producers.
The list of investment drivers for building new ammonia plants in the US over the last few years was short, beginning and ending with cheap natural gas. Markets change, however, and the investment drivers for the next generation of new ammonia plants might include low cost electrolyzers, low cost renewable power, carbon taxes, and global demand for ammonia as a carbon-free energy vector.
For this to make sense, however, ammonia needs to be produced without fossil fuel inputs. This is perfectly possible using Haber-Bosch technology with electrolyzers, but today's wind and solar power plants exist on a smaller scale than could support a standard (very big) Haber-Bosch plant. So, to produce renewable ammonia, small-scale ammonia production is essential.
This time series chart shows the capital intensity of today’s ammonia plants. Together, the data illustrate competitive advantages of alternative investment strategies, and demonstrate a shift away from the prior trend toward (and received wisdom of) monolithic mega-plants that rely on a natural gas feedstock.
As part of the sustainable agenda of the UK, the government, research institutions and various enterprises have looked for options to reduce the carbon footprint of the country while ensuring energy independence for several years. As a response, one of the alternatives has been to introduce the use of marine energy via the implementation of a barrage in the Severn Estuary or the development and implementation of Tidal Lagoons located around the Welsh coast. From these alternatives, the tidal lagoon concept seems to be most feasible.
Hybrid tidal and wind energy systems will produce vast amounts of energy during off-peak hours that will require the use of energy storage technologies - the size of each proposed tidal lagoon ranges close to ~1.5 GW. Currently, companies involved in the development of these complexes are thinking of batteries, pumped hydro, and ammonia as the potential candidates to provide storage for these vast amounts of energy.
Last month, a heavyweight consortium of local and global companies announced plans to collaborate on a project to design, build, operate, and evaluate a demonstration plant to produce "green ammonia" from water, air, and renewable energy in The Netherlands.
This is one practical outcome of last year's Power-to-Ammonia study, which examined the economic and technical feasibility of using tidal power off the island of Goeree-Overflakkee in Zuid-Holland to power a 25 MWe electrolyzer unit, and feed renewable hydrogen to a 20,000 ton per year green ammonia plant.
This new demonstration plant phase of the project will still be led by the original developer, Dutch mini-ammonia plant developer Proton Ventures. However, its partners in the venture now include Yara and Siemens, as well as speciality fertilizer producer Van Iperen, and local sustainable agricultural producer, the Van Peperstraten Groep.
On August 1, 2017 the Japan Government’s New Energy and Industrial Technology Development Organization (NEDO) announced that it will proceed with funding for the construction of a hydrogen production plant in Namie Township, about ten kilometers from the site of the Fukushima nuclear disaster. The project’s budget is not mentioned, but the installation is projected to be “the largest scale in the world” -- in other words, a real bridge to the future and not a demonstration project.
The project no doubt has a variety of motivations, not least the symbolic value of a renewable hydrogen plant rising in the shadow of the Fukushima Daiichi nuclear station. In economic terms, though, it appears to be a dead end. This is unfortunate because a similarly conceived project based on ammonia could be a true bridge-building step that aligns with leading-edge developments elsewhere in the world.
In the last 12 months ...
Researchers seeking to fire gas turbines with ammonia made significant strides toward realization of commercial-scale machines in both the U.K. and Japan. This means that electricity generation has become a realistic near-term use-case for ammonia energy.
In the last 12 months ...
The research community has made great progress toward solving the "selectivity challenge" in electrochemical ammonia synthesis. Although, rather than an actual solution, mostly what we have is a range of sophisticated work-arounds that succeed in making this problem moot.