The ammonia-fueled gas turbine (A-GT) seems destined to become one of the key technologies in the sustainable energy economy of the future. Siemens AG, for one, features the A-GT in its vision for “Green Ammonia for Energy Storage and Beyond” and the demonstration system that the company is building at the Rutherford Appleton Laboratory in the U.K. Last month Ian Wilkinson, Siemens’ Programme Manager for the demonstration project, spoke about the project’s progress at the 1st European Power to Ammonia® Conference in Rotterdam in The Netherlands. Although he devoted a slide to the A-GT, the detailed perspective came from another presentation at the conference. This one was delivered by Dr. Agustin Valera-Medina, a Senior Lecturer at Cardiff University, one of Siemens’ main green ammonia collaborators.
The maritime industry is beginning to show significant interest in using ammonia as a "bunker fuel," a sustainable alternative to the highly polluting heavy fuel oil (HFO) currently used in ships across the world.
In recent months, a firm of naval architects and a new maritime think tank have both been evaluating ammonia as a fuel. This includes a road map for future research, and collaborations for a demonstration project that will allow them to design and build a freight ship "Powered by NH3."
One of the many encouraging announcements at the recent Power-to-Ammonia conference in Rotterdam was the news that the Korea Institute of Energy Research (KIER) has extended funding for its electrochemical ammonia synthesis research program by another three years, pushing the project forward through 2019.
KIER's research target for 2019 is significant: to demonstrate an ammonia production rate of 1x10-7 mol/s·cm2.
If the KIER team can hit this target, not only would it be ten thousand times better than their 2012 results but, according to the numbers I'll provide below, it would be the closest an electrochemical ammonia synthesis technology has come to being commercially competitive.
“Carbon-free ammonia needs to be a significant contributor to the H2@Scale initiative.” This was one of the “key takeaways” offered by Steve Szymanski, Director of Business Development at the hydrogen generator company Proton On-Site, during his presentation at the H2@Scale Workshop that was held on May 23-24 at the University of Houston in the U.S. By the time Szymanski left the podium, ammonia energy had moved a good distance from the periphery of the H2@Scale conceptual map toward its center.
The Institute for Sustainable Process Technology (ISPT) recently published a detailed analysis of three business cases for producing renewable ammonia from electricity: Power to Ammonia. The feasibility study concludes that, in the near term, ammonia production using clean electricity will likely rely on a combination of two old-established, proven technologies: electrolysis and Haber-Bosch (E-HB). To reach this conclusion, however, the study also assessed a range of alternative technologies, which I summarize in this article.
In Australia this week, CSIRO announced funding for the "final stages of development" of its metal membrane technology to produce high-purity hydrogen from ammonia. The two year research project aims to get the technology "ready for commercial deployment," with industrial partners including Toyota and Hyundai.
On April 27 the on-line journal Science Advances published “Carbon-free H2 production from ammonia triggered at room temperature with an acidic RuO2/γ-Al2O3 catalyst.” The lead author, Katsutoshi Nagaoka, and his six co-authors are associated with the Department of Applied Chemistry at Oita University in Japan. The innovation featured in the paper could prove to be an important enabler of ammonia fuel in automotive applications.
Next month the print edition of Fuel Processing Technology will feature a paper entitled “Auto-ignition of a carbon-free aqueous ammonia/ammonium nitrate monofuel: a thermal and barometric analysis.” This title is provocative. First, what is this idea of a fuel composed of a mixture of ammonia and ammonium nitrate (AN)? If ammonia is a good fuel, is it made better with the addition of ammonium nitrate? Second, why is it aqueous? Is the presence of water a feature or a bug? Third, what is a monofuel and why is this term used when the fuel is a mixture of two molecular species? And finally, why is the paper ultimately about auto-ignition?
At ARPA-E's recent Energy Innovation Summit in Washington, DC, Program Director Grigorii Soloveichik presented his vision for the future of transportation: hybrid electric vehicles that combine the advantages of both plug-in battery and fuel cell technologies.
This "optimal solution" will require a new generation of fuel cell that is "fast, furious, and flexible." Fast, in terms of start-up / shut-down time. Furious, in terms of energy density. And flexible, in terms of fuel choice - specifically sustainable liquid fuels, like ammonia.
There will be many ways to make ammonia in the future and, regardless of breakthroughs in chemical catalysts and engineering design, genetically modified organisms will play an increasingly important role.
At this week's American Chemical Society meeting, Daniel Nocera from Harvard University introduced his new ammonia synthesis technology. It builds on his "artificial leaf" that produces and stores hydrogen using power from sunlight. Nocera's latest innovation is to couple this system with a microbe that naturally contains nitrogenase, the enzyme that fixes atmospheric nitrogen into ammonia.
The end result - a robust population of nitrogen fertilizer-emitting microbes - can be delivered to the soil simply by watering the plants.