The ammonia-fueled gas turbine (A-GT) seems destined to become one of the key technologies in the sustainable energy economy of the future. Siemens AG, for one, features the A-GT in its vision for “Green Ammonia for Energy Storage and Beyond” and the demonstration system that the company is building at the Rutherford Appleton Laboratory in the U.K. Last month Ian Wilkinson, Siemens’ Programme Manager for the demonstration project, spoke about the project’s progress at the 1st European Power to Ammonia® Conference in Rotterdam in The Netherlands. Although he devoted a slide to the A-GT, the detailed perspective came from another presentation at the conference. This one was delivered by Dr. Agustin Valera-Medina, a Senior Lecturer at Cardiff University, one of Siemens’ main green ammonia collaborators.
The maritime industry is beginning to show significant interest in using ammonia as a "bunker fuel," a sustainable alternative to the highly polluting heavy fuel oil (HFO) currently used in ships across the world.
In recent months, a firm of naval architects and a new maritime think tank have both been evaluating ammonia as a fuel. This includes a road map for future research, and collaborations for a demonstration project that will allow them to design and build a freight ship "Powered by NH3."
On April 27 the on-line journal Science Advances published “Carbon-free H2 production from ammonia triggered at room temperature with an acidic RuO2/γ-Al2O3 catalyst.” The lead author, Katsutoshi Nagaoka, and his six co-authors are associated with the Department of Applied Chemistry at Oita University in Japan. The innovation featured in the paper could prove to be an important enabler of ammonia fuel in automotive applications.
The Institute for Sustainable Process Technology recently published a feasibility study, Power to Ammonia, looking at the possibility of producing and using ammonia in the renewable power sector. This project is based in The Netherlands and is led by a powerful industrial consortium.
I wrote about the feasibility study last month, but it deserves closer attention because it examines three entirely separate business cases for integrating ammonia into a renewable energy economy, centered on three site-specific participants in the study: Nuon at Eemshaven, Stedin at Goeree-Overflakkee, and OCI Nitrogen at Geleen.
Over the next few years, the group intends to build pilot projects to develop and demonstrate the necessary technologies. Next month, however, these projects will be an important part of the Power-to-Ammonia Conference, in Rotterdam on May 18-19.
This article is the first in a series of three that aims to introduce each business case.
Next month the print edition of Fuel Processing Technology will feature a paper entitled “Auto-ignition of a carbon-free aqueous ammonia/ammonium nitrate monofuel: a thermal and barometric analysis.” This title is provocative. First, what is this idea of a fuel composed of a mixture of ammonia and ammonium nitrate (AN)? If ammonia is a good fuel, is it made better with the addition of ammonium nitrate? Second, why is it aqueous? Is the presence of water a feature or a bug? Third, what is a monofuel and why is this term used when the fuel is a mixture of two molecular species? And finally, why is the paper ultimately about auto-ignition?
The Institute for Sustainable Process Technology has just published a feasibility study that represents a major step toward commercializing renewable ammonia.
It examines the "value chains and business cases to produce CO2-free ammonia," analysing the potential for commercial deployment at three companies with existing sites in The Netherlands: Nuon at Eemshaven, Stedin at Goeree-Overflakkee, and OCI Nitrogen at Geleen. The project is called Power to Ammonia.
The shipping industry is beginning to evaluate ammonia as a potential "bunker fuel," a carbon-free alternative to the heavy fuel oil (HFO) used in maritime transport.
International trade associations are leading the effort to decarbonize the sector, in alignment with targets set by the Paris Climate Agreement. Their immediate challenge is simple to state but hard to solve: "ambitious CO2 reduction objectives will only be achievable with alternative marine fuels which do not yet exist." In the long-term, however researchers recognize that "fuel cell-powered ships are likely to dominate, drawing their energy from fuels such as hydrogen and ammonia."
On February 14 the Journal of Physical Chemistry published a paper entitled “Local Structures and Catalytic Ammonia Combustion Properties of Copper Oxides and Silver Supported on Aluminum Oxides.” The paper, by Satoshi Hinokuma of Kumamoto University in Kumamoto, Japan and four co-authors, reports on a catalyst system that is well adapted for use in ammonia energy applications.
Most of the ammonia energy projects I write about are in the research and development phase but, as I've said before, technology transfer from the academic lab to commercial deployment is moving swiftly - especially in Japan.
Last week, Nikkei Asian Review published two articles outlining plans by major engineering and power firms to build utility-scale demonstrations using ammonia as a fuel for electricity generation. Both projects aim to reduce the carbon intensity of the Japanese electrical grid, incrementally but significantly, by displacing a portion of the fossil fuels with ammonia. The first project will generate power using an ammonia-coal mix, while the second will combine ammonia with natural gas.
Hideaki Kobayashi, professor at the Institute of Fluid Science at Tohoku University in Sendai, Japan, has developed the world’s first technology for direct combustion of ammonia in a gas turbine. The advance was made in cooperation with the National Institute of Advanced Industrial Science and Technology (AIST) under a program led by Norihiko Iki.