Shimshon Gottesfeld’s paper The Direct Ammonia Fuel Cell and a Common Pattern of Electrocatalytic Processes leads with a big number: “A record power density of 450 mW/cm2 has been demonstrated for a direct ammonia fuel cell [DAFC] using an alkaline membrane electrolyte.” We know it’s big because it’s 80% higher than the 250 mW/cm2 that Gottesfeld’s team had achieved in the fall of 2017 and that Gottesfeld, Adjunct Professor of Chemical Engineering at the University of Delaware, reported at the November 2017 NH3 Energy+ Topical Conference.
In the last 12 months ...
IHI Corporation tested its 1 kW ammonia-fueled solid oxide fuel cell (SOFC) in Japan; Project Alkammonia concluded its work on cracked-ammonia-fed alkaline fuel cells (AFC) in the EU; the University of Delaware's project for low-temperature direct ammonia fuel cells (DAFC) continues with funding from the US Department of Energy's ARPA-E; and, in Israel, GenCell launched its commercial 4 kW ammonia-fed AFC with field demonstrations at up to 800 locations across Kenya.
"Ammonia for Power" is an open-access literature review that includes over 300 citations for recent and ongoing research in the use of ammonia in engines, fuel cells, and turbines, as well as providing references to decades of historical case studies and publications. The review, written by a consortium of ammonia energy experts from the University of Cardiff, University of Oxford, the UK's Science and Technology Facilities Council, and Tsinghua University in China, can be found in the November 2018 edition of Progress in Energy and Combustion Science.
I wrote earlier today about a new literature review on "Ammonia for Power," published in November 2018. As a companion piece to that article, I'd like to highlight another open-access literature review, this one published a few years before we launched Ammonia Energy, which focuses completely on the (perhaps unexpectedly) broad subject of direct ammonia fuel cells. The mini-review, "Ammonia as a suitable fuel for fuel cells," was published in the August 2014 edition of Frontiers in Energy Research, written by Rong Lan and Shanwen Tao of the University of Strathclyde in the UK.
This week, DNV GL published its annual Energy Transition Outlook, providing a long-term forecast for global energy production and consumption, and including a dedicated report describing its Maritime Forecast to 2050. This is the first forecast from a major classification society explicitly to evaluate ammonia as a maritime fuel.
By 2050, DNV GL predicts that 39% of the global shipping energy mix will consist of "carbon-neutral fuels," a category that include ammonia, hydrogen, biofuels, and other fuels produced from electricity. By 2050, these fuels will therefore have gained greater market share than oil, LNG, and battery-electric. If ammonia succeeds as the carbon-neutral fuel of choice in the shipping sector, this new demand will be roughly equivalent to 200 million tons of ammonia per year, more than today's total global production.
Last week, I wrote about a crucial new report that discusses four fuel technologies: batteries, hydrogen, ammonia, and nuclear. These could reduce the shipping sector's emissions in line with targets set in the IMO's Initial GHG Strategy. The report, Reducing CO2 Emissions to Zero, concludes that "all industry stakeholders ... need to get on with the job of developing zero CO2 fuels." This call to action should be consequential: it comes from the International Chamber of Shipping, an influential industry group that represents "more than 80% of the world merchant fleet."
This week, I provide an example of the kind of research required, with an update on a project that aims to demonstrate "the technical feasibility and cost effectiveness of an ammonia tanker fueled by its own cargo."
Although this project is still in its early days, I want to highlight three aspects that I believe will be crucial to its success. First, the work is being done by a consortium, bringing together many industry stakeholders, each with its own expertise and commercial interests. Second, the scope of research extends beyond conventional engine configurations to include not just new fuels but also new technology combinations; in other words, rather than assess new fuels in old engines, it aims to develop optimized propulsion designs for zero-emission fuels. And, third, its consideration of ammonia as a fuel begins with a comprehensive safety analysis.
GenCell Energy, the Israeli fuel cell manufacturer, has made two major announcements in the last month. In June, it unveiled its ammonia-fueled alkaline fuel cell system. In July, it announced its first commercial customer.
Its A5 Off-Grid Power Solution is a "nano power plant that operates fully independent of the grid." The first phase of product trials, using ammonia as a fuel to provide uninterruptible power to cell phone masts, will begin in Kenya by the end of this year, and "product roll-out" is expected in the second half of 2019.
Japanese manufacturing concern IHI reported on May 16 that it had “successfully generated 1 kW class power” from a direct ammonia solid oxide fuel cell. This is the latest milestone for a technology that could play a major role in the roll-out of Japan’s Hydrogen Society.
Twelve months ago, I wrote here that "the shipping industry is beginning to evaluate ammonia as a potential 'bunker fuel,' a carbon-free alternative to the heavy fuel oil (HFO) used in maritime transport." Around that time, I described the obstacle to adoption of ammonia fuel as an information gap, rather than a technology gap, because no new technology was required: the industry simply did not know about ammonia. This information gap had allowed the industry to believe that "CO2 reduction objectives will only be achievable with alternative marine fuels which do not yet exist." I'm glad to announce that this information gap is closing, and fast.
According to a report published last week by the International Transport Forum, the OECD's "think tank for transport policy," the use of "currently known technologies could make it possible to almost completely decarbonise maritime shipping by 2035." This conclusion requires the adoption of ammonia as a zero-carbon fuel.
Last month, an important new consortium in the Netherlands announced its intention to research and demonstrate "the technical feasibility and cost effectiveness of an ammonia tanker fuelled by its own cargo." This two-year project will begin with theoretical and laboratory studies, and it will conclude with a pilot-scale demonstration of zero-emission marine propulsion using ammonia fuel in either an internal combustion engine or a fuel cell.