At the 2017 NH3 Energy+ Conference, graduate student Doga Demirhan reported on an ongoing investigation at the Energy Institute at Texas A&M University. The work involved evaluation of options for an ammonia production system and concluded that biomass could be an economically viable feedstock under current, real-world conditions. This is a notable outcome. Just as notable is how it was reached.
I wrote recently about two pathways for ammonia production technology development: improvements on Haber-Bosch, or electrochemical synthesis.
Last week, I covered some of these Haber-Bosch improvements; next week, I'll write about electrochemical processes. This week, I want to write about some innovations that don't fit this two-way categorization: they don't use electrochemistry and they don't build upon the Haber-Bosch process, and that might be the only thing that links them.
At the recent NH3 Energy+ Topical Conference, Grigorii Soloveichik described the future of ammonia synthesis technologies as a two-way choice: Improvement of Haber-Bosch or Electrochemical Synthesis.
Two such Haber-Bosch improvement projects, which received ARPA-E-funding under Soloveichik's program direction, also presented papers at the conference. They each take different approaches to the same problem: how to adapt the high-pressure, high-temperature, constant-state Haber-Bosch process to small-scale, intermittent renewable power inputs. One uses adsorption, the other uses absorption, but both remove ammonia from the synthesis loop, avoiding one of Haber-Bosch's major limiting factors: separation of the product ammonia.
In late August, the day before the exciting solar eclipse, the Ammonia Economy symposium was held as part of the Energy and Fuels Division of the American Chemical Society (ACS) National Meeting in Washington DC. This marks the third gathering of Ammonia related research since 2015 at the national level ACS conference. This year, in addition to the important focus on chemistries for the utilization of ammonia, the rapidly developing field of homogeneous catalysts and biological processes for nitrogen fixation was included as a major theme.
“Carbon-free ammonia needs to be a significant contributor to the H2@Scale initiative.” This was one of the “key takeaways” offered by Steve Szymanski, Director of Business Development at the hydrogen generator company Proton On-Site, during his presentation at the H2@Scale Workshop that was held on May 23-24 at the University of Houston in the U.S. By the time Szymanski left the podium, ammonia energy had moved a good distance from the periphery of the H2@Scale conceptual map toward its center.
Last week, ARPA-E announced funding for eight technologies that aim to make ammonia from renewable electricity, air, and water.
The technological pathways being developed include adaptations of the Haber-Bosch process - seeking improvements in catalysts and absorbents - as well as novel electrochemical processes.
The American Institute of Chemical Engineers (AIChE) will present a Webinar on December 21 on "Distributed Ammonia Synthesis." The presenter will be Edward L. Cussler, Distinguished Institute Professor at the Chemical Engineering and Materials Science Department of the University of Minnesota.
Distributed ammonia synthesis is one focus related to ammonia energy at the University of Minnesota - but just one. In fact, UMinn is the locus of a unique and globally significant collection of research efforts that promise to have significant impacts in the ammonia industry and the broader energy sector.
NH3 Fuel Association President Norm Olson presented his paper “NH3 – the Optimal Liquid Transportation Fuel” on November 9 at the annual meeting of the American Institute of Chemical Engineers (AIChE). The AIChE meeting, held over six days in San Francisco, provided a wide-ranging perspective on the sustainable energy landscape that ammonia energy must compete within.
The team at the University of Minnesota announced last month the award of funding for a demonstration project entitled "Clean Vehicles Fueled by Hydrogen from Renewable Ammonia."
This project builds on years of research and investment in renewable ammonia at University of Minnesota, most visibly the prototype wind-to-ammonia production plant operating since 2014 at West Central Research and Outreach Center.
Their focus now, however, is shifting to the use of ammonia as a fuel. "The overall objective of the project is to displace up to 50% of the diesel fuel used in tractors with anhydrous ammonia produced from renewable resources."