At the recent NH3 Energy+ Topical Conference, Grigorii Soloveichik described the future of ammonia synthesis technologies as a two-way choice: Improvement of Haber-Bosch or Electrochemical Synthesis.
Two such Haber-Bosch improvement projects, which received ARPA-E-funding under Soloveichik's program direction, also presented papers at the conference. They each take different approaches to the same problem: how to adapt the high-pressure, high-temperature, constant-state Haber-Bosch process to small-scale, intermittent renewable power inputs. One uses adsorption, the other uses absorption, but both remove ammonia from the synthesis loop, avoiding one of Haber-Bosch's major limiting factors: separation of the product ammonia.
This morning in Beijing, China, the International Energy Agency (IEA) launched a major new report with a compelling vision for ammonia's role as a "hydrogen-rich chemical" in a low-carbon economy.
Green ammonia would be used by industry "as feedstock, process agent, and fuel," and its production from electrolytic hydrogen would spur the commercial deployment of "several terawatts" of new renewable power. These terawatts would be for industrial markets, additional to all prior estimates of renewable deployment required to serve electricity markets. At this scale, renewable ammonia would, by merit of its ease of storage and transport, enable renewable energy trading across continents.
The IEA's report, Renewable Energy for Industry, will be highlighted later this month at the COP23 in Bonn, Germany, and is available now from the IEA's website.
The Institute for Sustainable Process Technology (ISPT) recently published a detailed analysis of three business cases for producing renewable ammonia from electricity: Power to Ammonia. The feasibility study concludes that, in the near term, ammonia production using clean electricity will likely rely on a combination of two old-established, proven technologies: electrolysis and Haber-Bosch (E-HB). To reach this conclusion, however, the study also assessed a range of alternative technologies, which I summarize in this article.
Let’s say there is such a thing as the “hydrogen consensus.” Most fundamentally, the consensus holds that hydrogen will be at the center of the sustainable energy economy of the future. By definition, hydrogen from fossil fuels will be off the table. Hydrogen from biomass will be on the table but the amount that can be derived sustainably will be limited by finite resources like land and water. This will leave a yawning gap (in the U.S., 60-70% of total energy consumption) that will be filled with the major renewables -- wind, solar, and geothermal -- and nuclear energy.
This may be as far as the consensus goes today, but more detail is now emerging on the global system of production and use that could animate a hydrogen economy.
This week, an important new voice joined the chorus of support for renewable ammonia and its potential use as an energy vector - the International Energy Agency (IEA).
In his article, Producing industrial hydrogen from renewable energy, Cédric Philibert, Senior Energy Analyst at the IEA, identifies a major problem with the hydrogen economy: hydrogen is currently made from fossil fuels. But his argument for producing hydrogen from renewable energy leads almost inevitably to ammonia: "In some not-too-distant future, ammonia could be used on its own as a carbon-free fuel or as an energy carrier to store and transport energy conveniently."
The Institute for Sustainable Process Technology has just published a feasibility study that represents a major step toward commercializing renewable ammonia.
It examines the "value chains and business cases to produce CO2-free ammonia," analysing the potential for commercial deployment at three companies with existing sites in The Netherlands: Nuon at Eemshaven, Stedin at Goeree-Overflakkee, and OCI Nitrogen at Geleen. The project is called Power to Ammonia.
A recent opinion piece in The Japan Times predicts a "revolutionary disruption coming to the energy sector," and suggests that using ammonia for energy storage will prove to be "a game-changer at least on the scale of the shale oil and gas revolution."
Developers around the world are looking at using ammonia as a form of energy storage, essentially turning an ammonia storage tank into a very large chemical battery.
In the UK, Siemens is building an "all electric ammonia synthesis and energy storage system." In the Netherlands, Nuon is studying the feasibility of using Power-to-Ammonia "to convert high amounts of excess renewable power into ammonia, store it and burn it when renewable power supply is insufficient."
While results from Siemens could be available in 2018, it might be 2021 before we see results from Nuon, whose "demonstration facility is planned to be completed in five years." But, while we wait for these real-world industrial data, the academic literature has just been updated with a significant new study on the design and performance of a grid-scale ammonia energy storage system.
In recent months, research teams from both Canada and Italy have published comparative analyses of sustainable ammonia production pathways.
These projects aim to quantify the costs and benefits of combining Haber-Bosch with a renewable hydrogen feedstock. Both projects examine the carbon intensity of ammonia production but, while the Canadian study broadens its remit to a full life cycle analysis, including global warming potential, human toxicity, and abiotic depletion, the Italian study focuses primarily on energy efficiency.
The American Institute of Chemical Engineers (AIChE) will present a Webinar on December 21 on "Distributed Ammonia Synthesis." The presenter will be Edward L. Cussler, Distinguished Institute Professor at the Chemical Engineering and Materials Science Department of the University of Minnesota.
Distributed ammonia synthesis is one focus related to ammonia energy at the University of Minnesota - but just one. In fact, UMinn is the locus of a unique and globally significant collection of research efforts that promise to have significant impacts in the ammonia industry and the broader energy sector.