Australia’s national research organisation CSIRO is contributing valuable R&D across the hydrogen and ammonia value chains. At Ammonia Energy APAC 2023, we’ll hear updates on some key ammonia energy projects at CSIRO: small-scale production, combustion engines, and fuel cells, as well as an ongoing partnership with Fortescue Future Industries to develop & deploy metal membrane technology for ammonia cracking systems.

The quickfire presentation will focus on the direct use of ammonia as an energy carrier. The examples considered here include using ammonia in diesel engines for power generation applications and development of solid oxide fuel cells operating with ammonia.

This week: an ammonia-powered shipping network in northern Europe, Sluiskil update, green projects in Uruguay, green ammonia in Ireland: a new update!, Euronav to develop ammonia-powered tankers, ammonia part of Equinor's net-zero by 2050 strategy, H2Site to install first on-site crackers in France and updates from Australia.

South Korea has featured in many Ammonia Energy news updates, but often in a scatter gun fashion that lacked the momentum of ammonia energy announcements coming from the other side of the Korea Strait. Now, South Korea is ready to step out from Japan’s shadow as a clean energy innovator and deployer in its own right. We’re seeing the beginnings of a well-articulated strategy to achieve society-wide decarbonisation in South Korea, with a starring role for clean hydrogen and clean ammonia.

Last week we presented the first episode in our monthly webinar series: Ammonia Energy Live. Every month we’ll explore the wonderful world of ammonia energy and the role it will play in global decarbonisation - with an Australian twist. To kick things off we wanted to set the scene for 2021 and give you a sense of where the ammonia transition is at - key projects, key milestones and things to be excited about going forward. And, since this is an Australian-focused series, we wanted to explore what’s important about Australia to the ongoing work of the AEA.

This year’s Ammonia Energy Conference included a panel discussion on next-generation ammonia synthesis, moderated by Sarb Giddey (CSIRO, Australia), and featuring panelists Doug MacFarlane (Monash University, Australia), Karthish Manthiram (MIT, United States), and Michael Stoukides (Aristotle University of Thessaloniki, Greece). The panel discussed the direct fixation of nitrogen in the form of ammonia from water and air in a single electrochemical device, which is considered the “holy grail” of ammonia synthesis. During the panel, the participants gave their perspectives on the state of the art, and the obstacles and opportunities for progress.

Fortescue recently announced that it has signed a memorandum of understanding (MOU) with Hyundai Motor Company and CSIRO for the “development and future commercialisation” of its metal membrane technology. This technology, which produces high-purity compressed hydrogen from liquid ammonia, was demonstrated in 2018. It enables PEM fuel cell vehicles to refuel using hydrogen that is generated on demand from ammonia. At scale, this technology could enable an ammonia-based hydrogen production, storage, and distribution infrastructure, lowering the barriers to implementation of a national network of hydrogen filling stations. Now, “Hyundai will seek to demonstrate the viability of the technology for renewable hydrogen production and vehicle fuelling in Korea.”

Pandemic or no pandemic, the Australian chapter of the Ammonia Energy Association (AEA Australia) will hold a second edition of its Ammonia = Hydrogen 2.0 Conference this year. The event will be held on a virtual basis on August 27 and 28 from 1:00 to 5:00 p.m. (Australian Eastern Standard Time) each day. The conference tagline is “Building an energy export industry using Green Ammonia.” Its themes this year will be “green ammonia production — jobs for the regions;” “ammonia as maritime bunker fuel;” and “ammonia certification schemes.” The opening address, entitled “Ammonia — is it a fuel, or is it an energy carrier?” will be given by Alan Finkel, Chief Scientist of the Australian Government.

Earlier this month the on-line trade journal gasworld published an interview with CSIRO's Ani Kulkarni that illuminated a research program focused on solid oxide electrolysis technology. The takeaway is that the CSIRO program is making progress that can, in Kulkarni’s words, “elevate this technology from the lab bench to become cost-effective at an industrial scale.”

Last month the Council of Australian Governments Energy Council – “a Ministerial forum for the Commonwealth [of Australia], states and territories and New Zealand, to work together in the pursuit of national energy reforms” – issued a 137-page report entitled Australia’s National Hydrogen Strategy. For those focused on how ammonia energy will go from promising idea to practical reality, this is what the next step – the one after the discovery of ammonia's virtues as a hydrogen carrier – could look like. The Strategy is detailed, comprehensive, and concerned with both practical measures in the near term and the arc of progress over the long term. And embedded within it are three ideas that are likely to have on-going relevance for ammonia energy implementation.

ANNUAL REVIEW 2019: Ammonia is too often assumed to be only a fertilizer. This assumption overlooks other important uses for the chemical, large and small, in every corner of our economy. Some of the recent green ammonia announcements suggest that these other industries might, in fact, present better economic fundamentals for green ammonia investments than the fertilizer industry. Alternatively, these companies might have set their sights on becoming first movers in developing the commodities of the future. Time will tell but, if the last 12 months is any guide, the mining industry could be a force for change in the ammonia industry.

The Ammonia Energy Association Australia’s Ammonia = Hydrogen 2.0 Conference took place on 22-23 August 2019 in Melbourne, Australia. It attracted 115 attendees from industry, government, and research institutions. This is the first of two articles about the event; this article recaps the interactive panel sessions and the second article will highlight selected presentations. The panel discussions were placed at the end of the program so that important themes from the presentations could be highlighted and integrated. These themes included: 1) Building an energy export industry using green ammonia; 2) Green ammonia as a maritime bunker fuel; and 3) Green ammonia as grid scale energy storage – a battery to the nation.

ANNOUNCEMENT: The Australian chapter of the Ammonia Energy Association (AEA Australia) has announced details of its inaugural conference, which will take place on August 22 and 23, 2019, and will be held at CSIRO in Clayton, Victoria. Entitled "Ammonia = Hydrogen 2.0," the conference will focus on the role of ammonia within the Australian hydrogen economy, specifically "Building an energy export industry using Green Ammonia." In addition to a full program of talks by invited speakers, networking events will include panel discussions, a poster session, and the conference dinner. Registration for the event is now open, with an early booking discount available until July 5.

Last week Australia’s Commonwealth Scientific and Industrial Research Organisation (CSIRO) announced the formation of a partnership that will support commercialization of CSIRO’s high-purity ammonia-to-hydrogen conversion technology.  Michael Dolan, Principal Research Scientist for the ammonia-to-hydrogen project, had signaled such a development on the occasion of the technology’s first public demonstration in August 2018, saying in a contemporaneous Ammonia Energy post that the identity of “a major industrial partner” would be revealed shortly. The partner turns out to be Fortescue Metals Group (FMG).  A November 22 article in Business Insider Australia states that the company will invest “[AUD]$19.1 million [USD$13.8] in technology developed by the CSIRO to make hydrogen vehicles viable in a potential gamechanger for the transport industry.”

The 2018 NH3 Energy Implementation Conference, the first of its kind, took place on November 1 in Pittsburgh, Pennsylvania in the U.S. The focus of the Conference was on steps – current and future – that will lead to implementation of ammonia energy in the global economy.  At the highest level, the Conference results validated the relevance and timeliness of the theme.  In the words of closing speaker Grigorii Soloveichik, Director of the U.S. Department of Energy’s ARPA-E REFUEL Program, the Conference strengthened his confidence that “ammonia is a great energy carrier ... with billions of dollars of potential in prospective markets.”

Ammonia can play a significant role in fuelling the world’s growing fuel cell electric vehicle (FCEV) fleet through technologies which allow the decomposition of NH3, and subsequent extraction and purification of H2. CSIRO has recently demonstrated a pilot-scale ammonia-to-hydrogen system, incorporating an ammonia decomposition stage with a subsequent membrane-based hydrogen purification stage, at a rate of several kilograms of H2 per day. Through partnerships with an industrial gas producer and two FCEV manufacturers, the resulting H2 has been compressed and dispensed into FCEVs. System design, materials, performance and strategies for scale-up and demonstration will be discussed.

Ammonia is currently mostly produced by the highly energy and carbon-intensive Haber–Bosch process, which requires temperatures of 450–500 °C and pressures of up to 200 bar. The feedstock for this process is hydrogen from natural gas (NG), coal or oil, and nitrogen produced from air by cryogenic route or pressure swing adsorption (PSA). The share of NG, coal and fuel oil feedstock for the global production of ammonia is 72%, 22% and 4% respectively, contributing to approximately 420 million tons of CO2 emissions per annum, representing over 1% of global energy related emissions. The energy consumed for ammonia synthesis by…

In the last 12 months ... Ammonia Energy has published posts covering pertinent activity in 32 different countries.  In most of them, ammonia’s potential as versatile energy vector has reached the point of avowed interest from relevant institutions.  In a small handful, it has become a part of national policy.  But, as demonstrated in repeated instances throughout the year, nowhere is ammonia energy more robustly embraced than Australia.  The central argument behind this assertion is captured in the phrase, “the complete package,” as in “package of resources, policies, players, partners, and investments.”

In the last 12 months ... Consider the attributes that characterize a good hydrogen carrier: liquid state at ambient conditions; high volumetric and gravimetric energy density; low propensity to create lethal hazards when transported, stored, and used.  Now consider that ammonia is superior to hydrogen itself in every one of these areas.  Given this, it stands to reason that proponents of hydrogen fuel cells should embrace ammonia as a valuable enabling technology that can elevate the feasibility and improve the economics of fuel-cell-based systems.  And indeed this embrace became evident over the last year.

In the last 12 months ... If a “meme”, in the definition of British psychology professor Susan Blackmore, “is information copied from person to person, including words, stories, technologies, fashions, and customs,” then clearly there is a meme spectrum that has “esoteric knowledge” at one end and “the common wisdom” at the other.  Where does ammonia energy fall on this spectrum?  “Esoteric knowledge” it may once have been, but this is no longer the case with the concept’s first incursions into mainstream reporting this year.

NH3FA.Oz, the Australian chapter of the NH3 Fuel Association, held a meeting on August 30 in approximate observance of its one-year anniversary.  John Mott, one of the founders of NH3FA.Oz and a member of the NH3 Fuel Association’s Advisory Board, reported that more than two dozen stakeholders from academia, industry, and the public sector participated.  The meeting came on the heels of the rapid-fire release of three significant reports, and preceded by a week the announcement of an important set of research grants.  The meeting, the reports, and the announcement all made clear that ammonia  is fast becoming a fixture in Australian energy policy.

On August 8th Australia’s Commonwealth Scientific and Industrial Research Organization (CSIRO) gave a public demonstration of its newly developed ammonia-to-hydrogen fueling technology.  In an interview this week with Ammonia Energy, Principal Research Scientist Michael Dolan reported that the demonstration drew more media attention than any event in CSIRO’s history – “by a comfortable margin.”  The reporting sounded a set of celebratory themes, summed up by this headline from the Australian Broadcasting Corporation: Hydrogen fuel breakthrough in Queensland could fire up massive new export market.  The stories, in other words, focused on what the demonstration could mean for fuel cell vehicles (FCVs) and the Australian economy.  They did not penetrate to the heart of the matter which involved a practical development whose importance can be uniquely appreciated by the ammonia energy community.

Where will fuel cell vehicles (FCVs) first achieve critical mass?  Japan and California spring to mind as likely jurisdictions.  South Korea not so much.  That situation could change, though, with recent announcements from the Ministry of Trade, Industry, and Energy (MTIE) in Seoul.  In fact, planned public and private sector investments could push South Korea to the front of the FCV pack. But while hydrogen-related activity of this nature can create opportunities for ammonia energy, the question always looms: are the key players in the implementing jurisdiction aware of the enabling roles ammonia can play?  Hyundai is unquestionably a key player in South Korea’s FCV landscape, and, courtesy of its support for the Australian ammonia-to-hydrogen fueling demonstration that will kick off in August, Hyundai is certainly aware, and could even become a champion, of ammonia-based FCV fueling.

On July 13, Science magazine, the flagship publication of the American Association for the Advancement of Science (AAAS), published a 2,800-word “feature article" on ammonia energy. The article, headlined, “Liquid sunshine: Ammonia made from sun, air, and water could turn Australia into a renewable energy superpower,” is uniformly open-minded and upbeat.  Its opening section ends with a quote from Monash University Professor of Physics and Chemistry Doug MacFarlane; “’Liquid ammonia is liquid energy,’ he says. ‘It's the sustainable technology we need.’” MacFarlane helped launch the Australian chapter of the NH3 Fuel Association.

Toyota Motor Corporation announced on April 25 the launch of an effort called the Chita City and Toyota City Renewable Energy-Use Low-Carbon Hydrogen Project.  According to the company’s press release, the project is intended as a step toward “the realization of a hydrogen-based society spanning the entire region through mutual coordination and all-inclusive efforts.”  For ammonia energy advocates, the announcement had two elements of particular significance. First is the clear indication that Toyota Motor Corporation is embracing ammonia as a hydrogen carrier – although not as a motor fuel.  Second is the project’s stated intention to establish a “system in which Aichi Prefecture certifies low-carbon hydrogen objectively and fairly.”

One of Ammonia Energy’s “top ten” stories of 2017 described Australia’s early steps toward export of renewable hydrogen in the form of green ammonia.  The story said that “Agencies such as the Australian Renewable Energy Agency (ARENA) made it clear during the year that the country intends to build on [its historical] position” as a supplier of fossil energy to countries such as Japan.  ARENA took a tangible step in this direction on December 20, 2017 with the release of a Request for Proposal for a AUD$20 million (USD$16 million) renewable hydrogen R&D funding program.  Included in the scope, per ARENA’s 2017 Investment Plan, could be “demonstration of renewable production methods for transportable energy storage options (such as hydrogen or ammonia).”

The use of ammonia (NH3) as a hydrogen vector can potentially enable renewable energy export from Australia to markets in Asia and Europe. With a higher hydrogen density than liquid H2, plus existing production and transport infrastructure, and well-developed safety practices and standards, the financial and regulatory barriers to this industry are lower than for liquid H2 transport. The only significant technical barrier which remains, however, is the efficient utilisation of ammonia fuel at or near the point of use, either directly or through the production of H2. For H2 production from NH3, the purity of the product H2 is…

A new study has made a major addition to the available literature on the economic benefits of ammonia energy. This latest study, published by researchers from CSIRO in Australia, provides the data needed to define the round-trip efficiency of using ammonia as a sustainable fuel and hydrogen carrier.

In the last 12 months ... Groups in Australia, Japan, Denmark, the U.K., and the U.S. all made progress with technologies that can be used to convert ammonia to hydrogen at fueling stations. This means that hydrogen for fuel cell vehicles can be handled as ammonia from the point of production to the point of dispensing.

Dateline Sydney, August 22, 2017.   Industrial gas vendor Linde Group (under its BOC brand) confirms its participation in a previously announced Australian ammonia-energy project.  With the Commonwealth Scientific and Industrial Research Organization (CSIRO) in the lead, the project partners will build and operate a pilot-scale “ammonia-to-hydrogen cracking” facility that showcases CSIRO’s hydrogen purification membrane technology.  BOC/Linde will contribute goods and services valued at AUD$100,000 (USD$80,000) to the AUD$3.4 million project.

Ammonia energy is about the development of technology, but it is also about the mobilization of investment.  To be precise, it is about how evolving technology can attract investment and how investment enables technological evolution.  A dynamic of this nature is emerging in Australia, where recent citations of ammonia energy in two mainstream venues signal its arrival as a legitimate target for public- and private-sector investment.

One of the many encouraging announcements at the recent Power-to-Ammonia conference in Rotterdam was the news that the Korea Institute of Energy Research (KIER) has extended funding for its electrochemical ammonia synthesis research program by another three years, pushing the project forward through 2019. KIER's research target for 2019 is significant: to demonstrate an ammonia production rate of 1x10^-7 mol/s·cm². If the KIER team can hit this target, not only would it be ten thousand times better than their 2012 results but, according to the numbers I'll provide below, it would be the closest an electrochemical ammonia synthesis technology has come to being commercially competitive.

In Australia this week, CSIRO announced funding for the "final stages of development" of its metal membrane technology to produce high-purity hydrogen from ammonia. The two year research project aims to get the technology "ready for commercial deployment," with industrial partners including Toyota and Hyundai.

Over the last few weeks, I've written extensively about sustainable ammonia synthesis projects funded by the US Department of Energy (DOE). While these projects are important, the US has no monopoly on technology development. Indeed, given the current uncertainty regarding energy policy under the Trump administration, the US may be at risk of stepping away from its assumed role as an industry leader in this area. This article introduces seven international projects, representing research coming out of eight countries spread across four continents. These projects span the breadth of next-generation ammonia synthesis research, from nanotechnology and electrocatalysis to plasmas and ionic liquids.

An interesting article this week went behind the scenes at CSIRO to show how the Australian R&D lab is developing energy management systems to link renewable generation with storage technologies - including ammonia, as a chemical energy storage medium, for export to Asia.

Solar ammonia' could be the key to the sustainable energy economies of two nations. During his talk at the 2016 NH3 Fuel Conference, Keith Lovegrove, Head of Solar Thermal at IT Power Group in Australia, said that Japan and Australia have the opportunity to move their trade in energy onto a climate-friendly foundation. This would involve development of Australia's solar resources in a way that helps Japan ramp up its Strategy for Hydrogen & Fuel Cells in the coming decades.