ANNOUNCEMENT: The Japanese Government’s Cabinet Office and the Japan Science and Technology Agency have released an English-language video that summarizes the accomplishments of the Cross-Ministerial Strategic Innovation Promotion Program’s Energy Carriers initiative. The release coincides with the end-of-March conclusion of Energy Carriers’ work, and anticipates this month’s formal activation of the Green Ammonia Consortium.
Haldor Topsoe has greatly improved the near-term prospects for green ammonia by announcing a demonstration of its next-generation ammonia synthesis plant. This new technology uses a solid oxide electrolysis cell to make synthesis gas (hydrogen and nitrogen), which feeds Haldor Topsoe's existing technology: the Haber-Bosch plant. The product is ammonia, made from air, water, and renewable electricity.
The "SOC4NH3" project was recently awarded funds from the Danish Energy Agency, allowing Haldor Topsoe to demonstrate the system with its academic partners, and to deliver a feasibility study for a small industrial-scale green ammonia pilot plant, which it hopes to build by 2025. There are two dimensions to this technology that make it so important: its credibility and its efficiency.
The movement toward small-scale ammonia is accelerating for two reasons. First, small ammonia plants are flexible. And, second, small ammonia plants are flexible.
They are feedstock-flexible, meaning that they can use the small quantities of low-value or stranded resources that are widely available at a local scale. This includes flared natural gas, landfill gas, or wind power.
And they are market-flexible, meaning that they can serve various local needs, selling products like fertilizer, energy storage, or fuel; or services like resource independence, price stability, or supply chain robustness.
While the scale of these plants is small, the impact of this technology is big. As industry-insider publication Nitrogen+Syngas explained in its last issue, "as ammonia production moves toward more sustainable and renewable feedstocks the ammonia market is facing a potentially radical change."
Last week, OCP Group announced plans to develop green hydrogen and green ammonia as sustainable raw materials for use in fertilizer production. This includes building pilot plants in both Germany, already under construction, and Morocco, yet to begin construction, as well as "the possible establishment of an African Institute for Solar Ammonia."
McKinsey & Company, the global consulting firm, recently published a report that analyzes the "Decarbonization of industrial sectors," with a focus on the four heaviest emitters: cement, steel, ammonia, and ethylene production.
"We conclude that decarbonizing industry is technically possible ... We also identify the drivers of costs associated with decarbonization and the impact it will have on the broader energy system." Of course, "technical and economical hurdles arise," but the report provides valuable analysis of the economic levers that will be required.
In June, ThyssenKrupp announced the launch of its technology for "advanced water electrolysis," which produces carbon-free hydrogen from renewable electricity and water. This "technology enables economical industrial-scale hydrogen plants for energy storage and the production of green chemicals."
Two weeks later, in early July, ThyssenKrupp announced that it was moving forward with a demonstration plant in Port Lincoln, South Australia, which had been proposed earlier this year. This will be "one of the first ever commercial plants to produce CO2-free 'green' ammonia from intermittent renewable resources."
The German conglomerate is one of the four major ammonia technology licensors, so its actions in the sustainable ammonia space are globally significant.
On July 13, Science magazine, the flagship publication of the American Association for the Advancement of Science (AAAS), published a 2,800-word “feature article" on ammonia energy. The article, headlined, “Liquid sunshine: Ammonia made from sun, air, and water could turn Australia into a renewable energy superpower,” is uniformly open-minded and upbeat. Its opening section ends with a quote from Monash University Professor of Physics and Chemistry Doug MacFarlane; “’Liquid ammonia is liquid energy,’ he says. ‘It's the sustainable technology we need.’”
MacFarlane helped launch the Australian chapter of the NH3 Fuel Association.
As part of the sustainable agenda of the UK, the government, research institutions and various enterprises have looked for options to reduce the carbon footprint of the country while ensuring energy independence for several years. As a response, one of the alternatives has been to introduce the use of marine energy via the implementation of a barrage in the Severn Estuary or the development and implementation of Tidal Lagoons located around the Welsh coast. From these alternatives, the tidal lagoon concept seems to be most feasible.
Hybrid tidal and wind energy systems will produce vast amounts of energy during off-peak hours that will require the use of energy storage technologies - the size of each proposed tidal lagoon ranges close to ~1.5 GW. Currently, companies involved in the development of these complexes are thinking of batteries, pumped hydro, and ammonia as the potential candidates to provide storage for these vast amounts of energy.
Last week, in Part 1 of this series on electrochemical ammonia synthesis technologies, I quoted a recent article by researchers at MIT that identified avenues for future research and development. One option was a biomimicry approach, learning from "enzymatic catalysts, such as nitrogenases," which can "either be incorporated into or provide inspiration for the design of electrocatalytic processes."
The nitrogenase enzyme, nature's ammonia synthesis technology, was developed in an iterative innovation process, otherwise known as evolution, that took hundreds of millions of years to reach this level of efficiency. According to one group of electrochemists, who presented their results at the recent NH3 Energy+ conference, nitrogenase produces ammonia in nature with an enviable 75% process efficiency - so it's no surprise that they are basing their industrial technology on it.
During our NH3 Energy+ Topical Conference, hosted within AIChE's Annual Meeting earlier this month, an entire day of presentations was devoted to new technologies to make industrial ammonia production more sustainable.
One speaker perfectly articulated the broad investment drivers, technology trends, and recent R&D achievements in this area: the US Department of Energy's ARPA-E Program Director, Grigorii Soloveichik, who posed this question regarding the future of ammonia production: "Improvement of Haber-Bosch Process or Electrochemical Synthesis?"