Topic: Cracking Ammonia

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High Flow Ammonia Cracking between 400-600°C

By , , , and on November 12, 2019
Traditional ammonia cracking is achieved at 850-950 °C in the presence of a nickel catalyst. The reaction is highly endothermic, and maintaining these high temperatures at high flow rates of ammonia gas can be difficult. Here, we present work using our advanced ammonia synthesis catalyst in an ammonia cracking setup. We use a metallic monolith catalyst support to minimize pressure drop at high flow rates. Full NH3 cracking occurs at 600 °C, with the onset of cracking at 400 °C. An output flame can be achieved with a fully tunable ratio of hydrogen to ammonia, depending on the temperature setpoint…

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Material Discovery and Investigation of Novel Y Containing Ru Catalysts for Low Temperature Ammonia Decomposition

By , and on November 12, 2019
Liquid ammonia can be used as an alternative hydrogen carrier and can be decomposed over catalysts to create a high purity hydrogen stream for fuel cell applications. Ammonia decomposition is typically catalyzed using supported ruthenium catalysts. Current ruthenium catalysts are expensive and often require reaction temperatures of 650 °C to attain complete conversion [1]. For the hydrogen produced from ammonia decomposition to be efficiently used in proton exchange membrane fuel cells, operating temperatures need to be considerably lowered and effluent concentrations of ammonia need to be minimized to avoid poisoning of the membrane [2]. Therefore, it is of interest to…

Paper

Carbon-Free H2 Production from NH3 Triggered at Ambient Temperature with Oxide Supported Ru Catalysts

By , and on November 12, 2019
Hydrogen produced from renewable energy has received a lot of attentions as a clean energy and development of a hydrogen storage and transportation system using hydrogen carrier has been greatly demanded. Among different kinds of hydrogen carrier, NH3 is regarded as one of the promising candidates, due to high energy density, high hydrogen capacity, and ease of liquification at room temperature. Furthermore, a carbon-free hydrogen storage and transportation system could be realized by using NH3 as hydrogen carrier. In this system, hydrogen produced from NH3 is used in engines, fuel cells, and turbines. However, use of NH3 as a hydrogen…

Article

Engie, Siemens, STFC, and Ecuity awarded funding for green ammonia-to-hydrogen in UK

By on September 06, 2019
Last week, the UK Department for Business, Energy and Industrial Strategy (BEIS) announced a "£390 million government investment to reduce emissions from industry," with a focus on low-carbon hydrogen supply and clean steel production. As part of this investment, a consortium led by Ecuity Consulting that includes Siemens, Engie, and the Science & Technology Facilities Council (STFC), has been awarded £249,000 to perform "valuable research on the role of ammonia in the delivery of low cost bulk hydrogen for use in the UK energy system."

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GenCell A5 update: hydrogen power from ammonia fuel cells (“The Next Big Thing in Energy Production”)

By on July 18, 2019
GenCell Energy, an Israeli technology company, recently announced a research collaboration with Fraunhofer UMSICHT, a German research institute, that will deliver a "scale-up of the catalyst synthesis process" for cracking ammonia. This will enable GenCell "to produce large quantities of a novel inexpensive catalyst for generation of hydrogen from ammonia."

Article

CSIRO Partner Revealed for NH3-to-H2 Technology

By on November 28, 2018
Last week Australia’s Commonwealth Scientific and Industrial Research Organisation (CSIRO) announced the formation of a partnership that will support commercialization of CSIRO’s high-purity ammonia-to-hydrogen conversion technology.  Michael Dolan, Principal Research Scientist for the ammonia-to-hydrogen project, had signaled such a development on the occasion of the technology’s first public demonstration in August 2018, saying in a contemporaneous Ammonia Energy post that the identity of “a major industrial partner” would be revealed shortly. The partner turns out to be Fortescue Metals Group (FMG).  A November 22 article in Business Insider Australia states that the company will invest “[AUD]$19.1 million [USD$13.8] in technology developed by the CSIRO to make hydrogen vehicles viable in a potential gamechanger for the transport industry.”
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