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Article

Literature Review: Ammonia as a Fuel for Compression Ignition Engines

Stephen H. Crolius March 23, 2020

The diesel engine, also known as the compression ignition (CI) engine, has been a workhorse of the modern energy economy for more than a hundred years. Its role in the coming sustainable energy economy will be determined by its ability to co-evolve with climate-friendly fuels. Two researchers from the National Institute of Advanced Industrial Science and Technology in Japan have now examined the fit between ammonia and the CI engine. Pavlos Dimitriou and Rahat Javaid arrive at a two-part conclusion in their paper, “A review of ammonia as a compression ignition engine fuel,” published in January in the International Journal of Hydrogen Energy. Part one is good news: “Ammonia as a compression ignition fuel can be currently seen as a feasible solution.” Part two is a dose of qualifying reality: to manage emissions of N2O, NOx, and unburnt NH3, “aftertreatment systems are mandatory for the adaptation of this technology,” which means that ammonia-fueled CI engines are likely to be feasible “only for marine, power generation and possibly heavy-duty applications where no significant space constraints exist.”

Presentation

Synthesis and Assessment of Process Systems for Production of Ammonia Using Nitric Oxide in Combustion Exhaust Gas

Hideyuki Matsumoto Shotaro Ogawa Keisuke Kobayashi Tetsuya Nanba Shiro Yoshikawa Taku Tsujimura Hirohide Furutani

Recently, ammonia is regarded as an alternative fuel without carbon dioxide (CO2). Numerous studies have been performed using ammonia as a fuel. Iki and Kurata confirmed the working of a prototype for the ammonia gas turbine, where ammonia burned in an environmentally benign way to generate electricity, exhausting only water and nitrogen [1]. From the view of cycle of ammonia for the development of a society with low carbon, it is required to synthesize carbon-free ammonia (green ammonia) in small plants. This green ammonia can be synthesized using renewable energy, with hydrogen from electrolysis of water and nitrogen from pressure…

Presentation

New Technology of the Ammonia Co-Firing with Pulverized Coal to Reduce the NOx Emission

Takamasa Ito Hiroki Ishii Juwei Zhang Sakiko Ishihara Toshiyuki Suda

Ammonia is recognized as the new energy carrier and it is expected to be introduced into the society in a short time, since the infrastructures related to the ammonia, such as the mass production, transportation and storage are already introduced to produce the fertilizer for the agriculture. There is one technical issue, to use the ammonia in the direct combustion as the fuel for the electric power generation. It is the increase of the NO concentration in the exhaust gas. Ammonia contains the large amount of the nitrogen, comparing with any other fuels that human being has ever treated. Nitrogen…

Presentation

Performance of Ammonia/Natural Gas Co-Fired Gas Turbine with Two-Stage Combustor

Masahiro Uchida Shintaro Ito Toshiyuki Suda Toshiro Fujimori

Ammonia has several advantages as renewable energy career [1-3]. Regarding the manufacturing process, the Harbor-Bosch method is already established. For transportation, ammonia can easily be liquefied at room temperature. Therefore, both transportation and storage are much easier than in case of hydrogen. In utilization, ammonia is combustible and used as a carbon-free fuel. However, ammonia has different combustion characteristics from natural gas. For example, the nitrogen atom contained in ammonia molecule causes high NOx emission through fuel NOx mechanisms [3]. Laminar burning velocity of ammonia is much lower; it might increase unburnt ammonia emission and cause unstable operation of gas…

Presentation

Pure Ammonia Combustion Micro Gas Turbine System

Ekenechukwu Chijioke Okafor Osamu Kurata Norihiko Iki Takahiro Inoue Tadahiro Fujitani Yong Fan Takayuki Matsunuma Taku Tsujimura Hirohide Furutani Masato Kawano Keisuke Arai Akihiro Hayakawa Hideaki Kobayashi

To protect against global warming, a massive influx of renewable energy is expected. Although hydrogen is a renewable media, its storage and transportation in large quantity has some problems. Ammonia fuel, however, is a hydrogen energy carrier and carbon-free fuel, and its storage and transportation technology is already established. In the 1960s, development of ammonia combustion gas turbines was abandoned because combustion efficiency was unacceptably low [1]. Recent demand for hydrogen energy carriers has revived the interest in ammonia as fuel [2, 3]. In 2015, ammonia-combustion gas turbine power generation was reported in Japan using a 50-kW class micro gas…

Presentation

Duiker Combustion Engineers BV Stoichiometry-Controlled Oxidation (SCO) Technology for Industrial Ammonia Combustion

Albert Lanser

In recent years, the stoichiometry-controlled oxidation (SCO) concept has been developed by Duiker Combustion Engineers to handle the ammonia-rich streams from sulphur recovery units within refineries. These ammonia rich streams are considered as waste streams that need to be destroyed with low NOx emissions. Several full-scale commercial SCO units have already been designed, delivered, installed and put in operation on refinery sites across the world, firing pure ammonia or rich ammonia-containing flows. The SCO technology has been based upon staged combustion and turns out to be a robust process, which is easy to operate and responds fast to upset conditions.…

Presentation

Performance of Ammonia-Natural Gas Co-Fired Gas Turbine for Power Generation

Shintaro Ito Masahiro Uchida Shogo Onishi Soichiro Kato Toshiro Fujimori Hideaki Kobayashi

Ammonia is paid special attention as renewable energy carrier [1-3], because it offers advantages in generation, transportation and utilization. Haber-Bosch method is already established as ammonia generation method; large amount of ammonia is already used as fertilizer and chemical raw material. Ammonia can be liquefied at room temperature. Its transport and storage system are already established. Ammonia is cheaper to transport than hydrogen. Ammonia can be used as carbon-free fuel in internal combustion engines as alternative to conventional hydrocarbon fuels. However, it has different combustion characteristics. For example, the nitrogen atom contained in the ammonia molecule, causes high NOx emission…

Presentation

Experimental and Computational Study for Reduction of NOx Emissions in the Ammonia / Methane Co-Combustion in a 10 KW Furnace

Ryuichi Murai Ryohei Omori Takahiro Kitano Hidetaka Higashino Noriaki Nakatsuka Fumiteru Akamatsu Yuya Yoshizuru Jun Hayashi

There are severe issues on increasing amount of carbon dioxide (CO2) emission in the world. Many studies are devoted to alternative fuels. One of promising candidates is the utilization of ammonia which is zero emission of CO2, a hydrogen energy carrier, and also can be burned directly as a fuel. For direct combustion of ammonia in industrial furnaces, there were two issues which were weaker radiative heat flux and a huge amount of NOx emission compared with the combustion of methane. We already have reported [1] the solution of the former issue by using the oxygen enriched combustion. The objective…

Presentation

Optimization of the NOx Reduction Condition in the Combustion Furnace for the Combustion of "Heavy-Oil - NH3 System" Using CFD

Yuya Yoshizuru Takeshi Suemasu Masayuki Nishio Ryuichi Murai Fumiteru Akamatsu

In late years the discharge of the CO2 became the very big problem. The combustion of the fossil fuel in particular exhausts much CO2. Our project team (SIP) is intended to reduce CO2 by using NH3 (10%~30%) in substitution for heavy oil. The ‘SIP energy carriers’ was launched in 2014 (SIP: Strategic Innovation Promotion Program). Ammonia direct combustion team was formed. We conducted a co-research program with Osaka University in this project. We performed experiment of heavy oil – NH3 mixed combustion in the 10kW furnace. As the results, we obtained much experimental data. When we were combusted NH3 and…

Presentation

Two Stage Ammonia Combustion in a Gas Turbine like Combustor for Simultaneous NO and Unburnt Ammonia Reductions

Akihiro Hayakawa K.D. Kunkuma A. Somarathne Masaaki Tsukamoto Taku Kudo Hideaki Kobayashi

Ammonia is expected not only as a hydrogen energy carrier but also as a carbon free fuel. Recently, ammonia fueled gas turbine combustor was successfully demonstrated. However, large amount of NOx was produced when ammonia burns because ammonia includes nitrogen atom in the ammonia molecule. In addition, unburnt ammonia concentration in exhaust gas also needs to be reduced. In this study, we proposed a combustion concept in order to reduce NO and unburnt ammonia concentrations in the exhaust gas simultaneously in a gas turbine like model swirl combustor. In this concept, two stage (rich – lean) combustion was employed. Two…